\\ Species Tag: & 41011 & Name:& K41-atom \\ Version: & 1 & &$^2$S$_{1/2}$ ground state \\ Date: & Dec. 2014 & & $^2$P$_J$ $J$ = $\frac{1}{2}$,$\frac{3}{2}$ \\ Contributor:& B. J. Drouin & & \\ & & & \\ Lines Listed: & 11 & Q(300.0)=& 7.9998 \\ Freq. (GHz) $<$ & 7500000 & Q(225.0)=& 7.9997 \\ Max. J: & 1 & Q(150.0)=& 7.9996 \\ LOGSTR0= & -99.0 & Q(75.00)=& 7.9982 \\ LOGSTR1= & -5.0 & Q(37.50)=& 7.9984 \\ Isotope Corr.: & -1.167 & Q(18.75)=& 7.9968 \\ Egy. (cm$^{-1}$) $>$& 0.0000 & Q(9.375)=& 7.9935 \\ $\mu_e$ = & 6.3768 & A=& \\ $\mu_m$ = & 2.0 & B=& \headend The atomic potassium line at has been measured to a precision of 0.001 Hz 1. Chan et al. 1970. See archived line file for precise frequency. The transitions (a.k.a. $D_1$ and $D_2$ lines) to the $^2$P$_J$ levels are measured with Lamb-dip spectroscopy, 2. S. Falke, E. Tiemann, C. Lisdat, H. Schnatz, G. Grosche, 2006, Phys. Rev. A 74, 032503. All positions of the $^2$S$_{1/2}$-$^2$P$_{1/2}$ multiplet were reported in 2, however only the hyperfine free center and a single component of the $^2$S$_{1/2}$-$^2$P$_{3/2}$ multiplet were reported. For determination of the equivilent SPFIT operators, the $A_{3/2}$ and $B_{3/2}$ constants reported in [2] were used with the Casimir expression to determine calculated line centers for the remaining 5 transitions, these are used in the fit and artificially reduce the reduced rms. The fit includes a fixed value of a fictitious (and extremely large) value of the $\lq$ rotational' constant which serves to remove non-zero $N$ quanta from the prediction. The dipole moment for the $^2$S$_{1/2}$-$^2$P$_{J}$ transitions of $^{39}$K was assumed to be that of the $^2$S$_{1/2}$-$^2$P$_{3/2}$ transition given by U.I. Safranova and M.S. Safranova, Phys. Rev. A 78, 052504 2008. the value given therein, 5.7939, was converted to Debye from atomic units (14.726 D) and then an empirically determined spherical harmonic scaling factor of $\sqrt(16/3)$ was factored out of the input value for entry into the .int file (6.3768 D). This value reproduces the lifetime ($\tau$ = 26.5 ns) of the $^2$S$_{1/2}$-$^2$P$_{3/2}$ state well, Wang et al. J. Chem. Phys. 106(19):7899-7912, 1997 report a value of 26.37(5) ns. The other transition gives a lifetime 2$\times$ longer than reported, presumably due to the different degeneracies of the states.